Polycyclic Aromatic Hydrocarbons Environment Protection Authority, November 2012, reformatted June 2021 1. Polycyclic (or polynuclear) aromatic hydrocarbons (PAHs) comprise a group of similar organic compounds comprised of at least two benzene rings. They typically result from the incomplete Method 8310 provides high performance liquid chromatographic (HPLC) conditions for the detection of ppb levels of certain polynuclear aromatic hydrocarbons. Prior to use of this method, appropriate sample extraction techniques must be used. A 5- to 25-uL aliquot of the extract is injected into an HPLC, and compounds in the effluent are detected Chapter 5.9 Polycyclic aromatic hydrocarbons (PAHs) General description Polycyclic aromatic hydrocarbons (PAHs) are a large group of organic compounds with two or more fused aromatic rings. They have a relatively low solubility in water, but are highly lipophilic. Most of the PAHs with low vapour pressure in the air are adsorbed on particles. The determination of polycyclic aromatic hydrocarbons in soil by dichloromethane extraction using gas chromatography with mass spectrometric detection . 1 Introduction 6. 2 Performance characteristics of the method 6. 3 Principle 7. 4 Hazards warning and safety precautions 7. 5 Reagents 8. 6 Apparatus 10. 7 Sample collection and storage 11 A polynuclear aromatic hydrocarbon is a hydrocarbon made up of fused aromatic ring molecules. These rings share one or more sides and contain delocalized electrons. Another way to consider PAHs is molecules made by fusing two or more benzene rings.Polynuclear aromatic hydrocarbon molecules contain only carbon and hydrogen atoms. Properties A polycyclic aromatic hydrocarbon (PAH) is a class of organic compounds that is composed of multiple aromatic rings.Simplest representatives naphthalene, having two aromatic rings and the three-ring compounds anthracene and phenanthrene.PAHs are uncharged, non-polar and planar. Many are colorless. Many of them are found in coal and in oil deposits, and are also produced by the combustion of PDF | On Feb 7, 2018, Abiodun Olagoke Adeniji and others published Analytical Methods for Polycyclic Aromatic Hydrocarbons and their Global Trend of Distribution in Water and Sediment: A Review Proximal Input of Polynuclear Aromatic Hydrocarbons (PAHs) in Groundwater Sources of Okrika Mainland, Nigeria 851 shaken for 5 minutes and allowed to stand for another 20 minutes. Layers were formed that separated the extract (the top layer) from the lower layer (which was discarded) and the extract collected for GC analysis in a glass vial. 2.7. coal and contain polynuclear aromatic hydrocarbons (PNA's). These hydrocarbons sublime readily, thereby increasing the amounts of carcinogenic compounds in the working areas. Epidemiologic evidence suggests that workers intimately exposed to the products of combustion or distillation of bituminous coal are at risk of cancer at many sites. Huckel formulated a rule to identify aromatic compounds that is known as Huckel's rule: 1. Aromatic compounds should be cyclic. 2. The compound should have a planar structure. 3. There should be delocalized πelectrons in the compound. 4. There should be (4n + 2) pi electrons in the compound. The value of n =0, 1, 2, 3… 13 This method allows for determination of polynuclear aromatic hydrocarbons (PAHs) in municipal and industrial discharges as provided u
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